A double Fourier analysis of the experimental data has been carried out-for the zones about the a, b and c crystal axes, and the results are expressed in figures which give the projection of the structure …
Naphthalene dioxygenase (NDO) from Pseudomonas sp., the only RDO for which a crystal structure is known , oxidizes naphthalene tocis-(1R,2S)-dihydroxy-1,2-dihydronaphthalene . Crystalline Structure of Naphthalene. Herein, the crystal structure of 1,8-dibenzoyl-2,7-diphenoxynaphtahlene, (I), is reported and its structural features are discussed through comparison with the homologues, 1,8-bis(4-fluorobenzoyl)-2,7-diphenoxynaphthalene (Hijikata et al., 2012 ) and 1,8-dibenzoyl-2,7-dimethoxynaphthalene … Single doses of 0 or 300 mg/kg 2-methylnaphthalene were administered to male mice by intraperitoneal injection, with sacrifice 24 hours later. Moreover, the π–π contacts between the naphthalene rings, may further consolidate the structure, with range of centroid– centroid distances = 3.5863 (9)—3.8048 (9) Å. The present observations do not indicate that 2-methylnaphthalene must be classified as potential genotoxic substance.
The enzyme has an α 3 β 3 composition, and each α subunit contains a Rieske [2Fe-2S] center and mononuclear iron at the active site. strain NCIB 9816-4 (NDO-O(9816-4)). O interactions.
ANIMAL STUDIES: 2-Methylnaphthalene is an eye and skin irritant in rabbits. A comprehensive X-ray investigation of the crystal structure of naphthalene is described, in which all the reflexions that lie within the reach of Cu Kα radiation have been examined. Here we examine the structural changes induced by mutation of Phe-352 in naphthalene 1,2-dioxygenase from Pseudomonas sp. Moving-film photographic methods and visual estimates of intensities by independent observers were employed. Structure, properties, spectra, suppliers and links for: Naphthalene, 91-20-3. 679 Fourier Analysis (Tables and Diagrams).
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